Save for the hydrogen and helium in the universe, which are thought to have been mostly produced in the Big Bang, most chemical elements are thought to have been produced by later processes.
These processes are divided into:
cosmic ray spallation (important for lithium, beryllium and boron, though some of these may have formed in the Big Bang), and
stellar nucleosynthesis which produces all elements heavier than boron (with carbon being the first of this series). The very heaviest elements (those beyond element 94, plutonium) decay with half lives too short to allow them to be observed naturally on Earth.
In total, 118 elements have been characterized as of March 2010, and new elements of higher atomic number are "discovered" from time to time, as new synthetic products of artificial nuclear reactions. Of the known elements, the first 92 occur naturally on Earth. Of these, oxygen is the most abundant element in the Earth's crust. About 80 elements have stable isotopes: namely all elements with atomic numbers 1 to 82, except elements 43 and 61 (technetium and promethium). About half of the 80 stable elements are expected to be radioactive with such long half lives that their decay happens only in theory, and is too slow to have yet been detected by experiment (see the list of nuclides). These elements (such as bismuth, only recently measured as unstable) have half lives at least 100 million to 1000 million times longer than the estimated age of the universe.
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